Your first day at a new job is a small test. Dressing too formally suggests you have not understood the company culture, while dressing too casually is remembered as carelessness. The best choice is an outfit you can adjust easily: a shirt and trousers in a calm colour, plus a blazer you can take off or put on. A tie is usually unnecessary, but it is worth keeping one to hand in case of an unplanned meeting.
Your industry matters a lot. In finance, law or consulting, business casual often means business attire without a tie. In tech and creative fields you can allow more softness in construction and fabric, but clean lines still count: sleeves that fit, a collar that holds its shape and well-kept shoes.
So does your calendar. A presentation, a promotion discussion, a client meeting or a conference calls for a more “business” version: muted colours, a classic shirt and proper shoes. On a Friday, when the office is more relaxed, you can dial it down half a step while staying within an office look.
One more simple test: look at photos from company conferences, panels and partner meetings, not from team parties. They show how the company wants to be seen from the outside, and even a relaxed office outfit is, to some degree, outward-facing, because it builds trust.