Construction and proportions matter. The blazer should sit evenly on the shoulders, not pull across the shoulder blades, and the lapels should lie flat. A half-canvas construction, with canvas sewn in from the shoulders to the middle of the chest, works well: the jacket holds its shape without being stiff and moulds to your body over time. This matters because a soft polo can't create shape on its own; the blazer has to do it.
A good example is this navy wool blazer with patch pockets, a half-canvas jacket with a slightly relaxed fit. The patch pockets give it a more casual character that suits a knit. If you want something lighter still, read how to choose an unstructured summer blazer.
A double-breasted blazer can also work with a polo, but the effect is stronger and more formal. Wear it buttoned, with a plain polo in a calm colour.
As for colour, navy and grey are the easiest to start with, because they work with most polos. A navy blazer with a white polo suits a meeting, a restaurant or a less formal family occasion when you don't want a full suit. You will find more ideas in our article on outfits with a navy blazer. A grey blazer goes well with blues and pastels and has a more daytime feel.
Combine patterns with restraint. With a check blazer, choose a plain polo: a light blue or navy polo, for example, suits this light grey wool check blazer for everyday wear. If the polo has a pronounced knit texture, the blazer can be plain or a subtle mélange. The rule is simple: one piece leads, the other stays in the background.
Watch the blazer's length too: it should cover your seat. Too short, worn with an untucked polo, it looks cut off; too long, it overwhelms a relaxed outfit.